Ceramic green sheet, ceramic green sheet laminate, production method of ceramic green sheet, and production method of ceramic green sheet laminate

ABSTRACT

The present invention provides a ceramic green sheet with a thin flat plate shape obtained by molding and solidifying a ceramic slurry, which contains a ceramic powder, dispersion medium, and gelling agent, into a thin flat plate. The ceramic green sheet partially includes a body that is obtained by molding and solidifying a conductor paste, which becomes a conductor later, and the body is exposed on a part of each of the both surfaces of the sheet. Plural ceramic green sheets described above are produced. The plural ceramic green sheets are successively stacked and press-bonded in the thickness direction in such a manner that the bodies included in the respective sheets are connected to each other for all combinations of the adjacent two sheets. As a result, a ceramic green sheet laminate is formed, which includes one body that is obtained by connecting the bodies included in the respective sheets.

BACKGROUND OF THE INVENTION

1. Field of the Invention

The present invention relates to a ceramic green sheet, a ceramic greensheet laminate, a production method of a ceramic green sheet, and aproduction method of a ceramic green sheet laminate.

2. Description of the Related Art

As one of production methods of a ceramic green body that is the statebefore a ceramic body is fired, there has conventionally been proposed amethod of producing a ceramic green body. In this method, a ceramicslurry containing a ceramic powder, a dispersion medium, and a gellingagent is subject to molding in a mold, and the resulted molded ceramicslurry is solidified (gelated) to form a ceramic green body (see, forexample, WO 2004/032581). This method is referred to as a gelcastingprocess.

SUMMARY OF THE INVENTION

In recent years, there has been proposed a technique for forming aceramic green sheet laminate serving as the ceramic green body. In thistechnique, a flat-plate ceramic green sheet is formed with thegelcasting process, and two or more ceramic green sheets are stacked inthe thickness direction so as to form the ceramic green sheet laminate.

The present inventors have found that, when the technique describedabove is employed, a conductor (electronic components such as coil,inductor, coupler, antenna, etc.) having a complicated three-dimensionalshape, and a space (cavity) can easily be formed by containing a body,which is made of a precursor of the conductor, during the process offorming each of the ceramic green sheets.

The ceramic green sheet according to the present invention has aflat-plate structure having a uniform thickness that is obtained bymolding and solidifying a ceramic slurry, which contains a ceramicpowder, dispersing medium, and gelling agent, into a flat-plate shape.The ceramic green sheet is characterized by partially including a bodythat is obtained by molding and solidifying a paste, which is made of acomponent different from the component of the ceramic slurry, whereinthe body is exposed on a part of each of both surfaces of the ceramicgreen sheet. For example, the ceramic slurry contains a component thatis solidified through gelation by a urethane reaction.

The body is composed of, for example, a precursor of the conductor. Theprecursor becomes the conductor when the ceramic sheet is formed throughthe firing of the ceramic green sheet. The body may also be composed ofa component (e.g., resin component, or the like, and referred to as“removed components through volatilization” below) that is totallyremoved through the volatilization when the ceramic sheet is formed byfiring the ceramic green sheet. The body may also be composed of aprecursor of the ceramic, which precursor becomes the ceramic when theceramic sheet is formed by firing the ceramic green sheet.

In the body, the portion that is exposed on a part of one of bothsurfaces of the ceramic green sheet and the portion that is exposed on apart of the other one of both surfaces of the ceramic green sheet arenot connected to each other. In this case, when the body is composed ofthe precursor of the conductor, a condenser having the ceramicinterposed between the conductors that are arranged so as to be apartfrom each other by a predetermined distance can be formed during theprocess of forming the ceramic sheet through the firing of the ceramicgreen sheet.

In the body, the portion that is exposed on a part of one of bothsurfaces of the ceramic green sheet and the portion that is exposed on apart of the other one of both surfaces of the ceramic green sheet may beconnected to each other. In this case, it is preferable that, for someor all combinations of the adjacent two ceramic green sheets in theceramic green sheet laminate having two or more ceramic green sheetslaminated in the thickness direction, the portion of the body that iscontained in one of the two adjacent ceramic green sheets and exposed tothe side facing the other of the two adjacent ceramic green sheets andthe portion of the body that is contained in the other of the twoadjacent ceramic green sheets and exposed to the side facing the one ofthe two adjacent ceramic green sheets are connected to each other.

By virtue of this structure, when the body is composed of the precursorof the conductor, for example, an electronic component (e.g., coil,inductor, coupler, antenna, etc.) having continuous complicatedthree-dimensional shape can be formed when the ceramic sheet is formedthrough the firing of the ceramic green sheets. Alternatively, when thebody is made of the “removed components through volatilization”, forexample, a space (cavity) having continuous complicatedthree-dimensional shape can be formed when the ceramic sheet is formedthrough the firing of the ceramic green sheets.

The ceramic green sheet according to the present invention is producedas described below, for example. Firstly, a paste is molded andsolidified on a plane of a first molding die having the plane so as toform a body having a predetermined shape. Then, the first molding dieand a second molding die having a plane are arranged such that the planeof the first molding die on which the body is formed and the plane ofthe second molding die face each other in parallel with each other witha gap, and the top surface of the body is brought into contact with theplane of the second molding die. Next, a ceramic slurry, which containsa ceramic powder, dispersion medium, and gelling agent and is made of acomponent different from the paste, is filled in the space formedbetween the planes of the first and second molding dies, in order tomold the ceramic slurry into a thin flat plate. Then, the molded ceramicslurry is solidified (thereafter, the first and second molding dies areremoved).

By virtue of this process, the ceramic green sheet having a thin flatplate shape and having uniform thickness according to the presentinvention (i.e., the ceramic green sheet partially including the bodyhaving the predetermined shape, wherein the body is exposed on a part ofeach of both surfaces of the ceramic green sheet) can be obtained. Inthis case, the portion of the body that is exposed on a part of one ofboth surfaces of the ceramic green sheet and the portion of the bodythat is exposed on a part of the other surface of the ceramic greensheet are connected to each other.

In the process described above, the ceramic slurry is molded into a thinflat plate with the body being formed on only the first molding die ofthe first and second molding dies. On the other hand, the ceramic slurrymay be molded into a thin flat plate with the body being formed on boththe first and molding dies.

In this case, the ceramic green sheet is produced as described below,for example. Firstly, a first paste is molded and solidified on a planeof a first molding die having the plane so as to form a first bodyhaving a first shape. Then, a second paste is molded and solidified on aplane of a second molding die having the plane so as to form a secondbody having a second shape. Next, the first molding die and the secondmolding die are arranged such that the plane of the first molding die onwhich the first body is formed and the plane of the second molding dieon which the second body is formed face each other in parallel with eachother with a gap. Next, a ceramic slurry, which contains a ceramicpowder, dispersion medium, and gelling agent and is made of a componentdifferent from the first and the second pastes, is filled in the spaceformed between the planes of the first and second molding dies, in orderto mold the ceramic slurry into a thin flat plate. Then, the moldedceramic slurry is solidified (thereafter, the first and second moldingdies are removed).

According to this process, the ceramic green sheet having a thin flatplate shape and having uniform thickness according to the presentinvention (i.e., the ceramic green sheet partially including the bodyhaving the predetermined shape, wherein the body is exposed on a part ofeach of both surfaces of the ceramic green sheet) can be obtained.

In this case, when the first and the second molding dies are arranged soas to be opposite to each other in parallel in such a manner that thetop surfaces of the first and the second bodies are brought into contactwith each other, the portion of the body exposed to a part of one ofboth surfaces of the ceramic green sheet and the portion of the bodyexposed on a part of the other surface of the ceramic green sheet areconnected to each other. On the other hand, when the first and thesecond molding dies are arranged so as to be opposite to each other inparallel in such a manner that the top surfaces of the first and thesecond bodies are apart from each other, the portion of the body exposedto a part of one of both surfaces of the ceramic green sheet and theportion of the body exposed on a part of the other surface of theceramic green sheet are not connected to each other.

The ceramic green sheet laminate according to the present invention isproduced as described below, for example. Firstly, only the secondmolding die is removed from the respective two or more ceramic greensheets, which are formed by the production process described above andhave the first and the second molding dies adhered thereon.Subsequently, the planes of two ceramic green sheets, which are exposedsince the second molding dies are removed, are press-bonded to form aceramic green sheet laminate having two ceramic green sheets describedabove. Then, only one of two first molding dies adhered on both ends ofthe ceramic green sheet laminate in the thickness direction is removed.Thus, the ceramic green sheet laminate in which the number of thelaminated layers is 2 can be obtained (by removing the remaining onefirst molding die afterward).

Alternatively, (in the ceramic green sheet laminate having the remainingone first molding die adhered thereon, wherein the number of thelaminated layer is 2), the plane of the ceramic green sheet laminatethat is exposed since the first molding die is removed and the plane,which is exposed since the second molding die is removed, of theremaining ceramic sheet that has not yet been laminated are press-bondedto form a new ceramic green sheet laminate in which the number of thelaminated layers is increased only by 1. Further, the only one of twofirst molding dies adhered on both ends of the new ceramic green sheetin the thickness direction is removed. This procedure is repeated morethan once. Thus, the ceramic green sheet in which the number of thelaminated layers is 3 or more can be obtained (by removing the remainingone first molding die afterward).

In this manner, the ceramic green sheet having the first molding dieadhered thereon is successively stacked. Thus, the ceramic green sheetsare successively stacked only by holding the first molding die, notholding the ceramic green sheet itself. As a result, the ceramic greensheet is easy to handle, and further, the deformation or the like of theceramic green sheet, which can be generated due to the direct holding ofthe ceramic green sheet, can be prevented.

In the production process of the ceramic green sheet laminate accordingto the present invention, it is preferable that the force in thethickness direction needed to separate the press-bonded ceramic greensheets is greater than the force in the thickness direction needed toseparate the first molding die, which is adhered onto the ceramic greensheet, from the ceramic green sheet, and the force in the thicknessdirection needed to separate the first molding die, which is adheredonto the ceramic green sheet, from the ceramic green sheet is greaterthan the force in the thickness direction needed to separate the secondmolding die, which is adhered onto the ceramic green sheet, from theceramic green sheet.

By virtue of this structure, it can be prevented that the first moldingdie, not the second molding die, is removed in the process of removingonly the second molding die from each of the ceramic green sheets havingthe first and second molding dies adhered thereon. Additionally, it canbe prevented that the first molding die is not removed but thepress-bonded ceramic green sheets are separated from each other in theprocess of removing the first molding die from the ceramic green sheetlaminate that is obtained by press-bonding the ceramic green sheets.

The force in the thickness direction needed to separate (release) theceramic green sheet molded on the plane (molding surface) of the moldingdie from the molding surface is referred to as a “mold release force”.The magnitude relation between the mold release force involved with thefirst molding die and the mold release force involved with the secondmolding die can be adjusted by performing a surface treatment to theplane of the first molding die and/or the plane of the second moldingdie, or by applying a mold release agent onto the plane of the firstmolding die and/or the plane of the second molding die. In this case, afluorine resin or wax is preferably used as the mold release agent. Afluorine resin coating is preferably performed as the surface treatment.The fluorine resin coating may be directly performed on the plane of thedie or may be performed with a predetermined undercoating, plating, andalumite treatment on the plane.

More specifically, a film is formed beforehand through the applicationof the mold release agent or the surface treatment on the plane of eachof the first and second molding dies before the body is formed on theplane of the first molding die or before the first and the second bodiesare formed on the planes of the first and the second molding dies. Byvirtue of this process, the magnitude relation between the mold releaseforce involved with the first molding die and the mold release forceinvolved with the second molding die can be adjusted by making the typesof the films different.

For example, when the fluorine resin is used as the mold release agent,the ceramic green sheet can be released (the ceramic green sheet isreleasable) by boundary separation with very small mold release force ateven room temperature (without damaging the ceramic green sheet. Whenthe wax is used as the mold release agent, the ceramic green sheet canbe released by heating and melting the wax, or by damaging the waxitself at room temperature. Therefore, the mold release force is greatat room temperature. When the nickel plating containing a fluorine resinis used as the surface treatment (coating), the ceramic green sheet canbe released, but the mold release force is great.

In general, the relationship of “mold release force in the case of thewax”>“the mold release force in the case of the nickel platingcontaining a fluorine resin”>“mole release force in the case of thefluorine resin” is established at room temperature. When the type of thefilm, formed on the respective planes of the first and second moldingdies according to the application of the mold release agent or thesurface treatment, is made different, the magnitude relation between themold release force involved with the first molding die and the moldrelease force involved with the second molding die can be adjusted (evenif the thickness of the film is the same).

The magnitude relation between the mold release force involved with thefirst molding die and the mold release force involved with the secondmolding die can also be adjusted by making the methods of applying themold release agent different. The mold release agent is applied in orderto form the films.

Examples of the method of applying the mold release agent include aspraying method, dipping method, brush coating method, etc. The portionwhere the surface of the base of the molding die is exposed on the planeof the molding die on which the film is formed is referred to as a “baseexposed portion”. On the base exposed portion, the base of the moldingdie and the ceramic green sheet are in direct contact with each other.This acts in the direction of increasing the mold release force.Specifically, the greater the total area of the base exposed portion is,the more the mold release force increases. The liquid obtained bydissolving the mold release agent (solid) into a solvent (organicsolvent or the like), which is used for applying the mold release agent,is referred to as “mold-release-agent solution”, and the concentrationof the mold release agent in the mold-release-agent solution is merelyreferred to as “concentration of the mold release agent”.

The spraying method and the dipping method are compared. In general, anultrathin film having relatively a uniform thickness can be formedaccording to the dipping method. On the other hand, the thickness of thefilm becomes non-uniform according to the spraying method, compared tothe case of the dipping method. This is based upon the reason describedbelow. Specifically, the state of the film formed by applying the moldrelease agent with the spraying method is relatively sensitive to theconcentration of the mold release agent, opening degree of a valveportion for adjusting the discharge rate (flow rate of the dischargedspray), temperature of the molding die, etc. When the appliedmold-release-agent solution is difficult to be dried, such as when thetemperature of the molding die is low or when the amount of thedischarge liquid is great, the flow (dripping) or aggregation of themold-release-agent solution is generated. Accordingly, theirregularities are easy to generate on the surface of the formed film.On the contrary, when the applied mold-release-agent solution is easy tobe dried, such as when the temperature of the molding die is high orwhen the amount of the discharge liquid is small, the solvent isvolatilized before the level of the mold-release-agent solution isleveled (smoothed). Therefore, the irregularities are also easy togenerate on the surface of the formed film. Anyway, the irregularitiesare easy to generate on the surface of the film, and hence, thethickness of the film is non-uniform in the case of the spraying method,compared to the dipping method. This means that the surface area of thefilm is increased in the spraying method compared to the dipping method.By virtue of this, the mold release force is increased more in thespraying method than in the dipping method.

Additionally, since the ultrathin film having relatively a uniformthickness can be formed in the dipping method as described above, the“base exposed portion” can be formed on only a great number ofmicroscopic protrusion portions on the plane that correspond to thesurface roughness of the plane (molding surface) of the molding die. Inother words, only a great number of microscopic “base exposed portions”are dispersed, while relatively large “base exposed portions” aredifficult to be formed. On the other hand, the thickness of the filmbecomes non-uniform in the spraying method as described above.Therefore, when the ultrathin film is formed, the relatively large “baseexposed portions” are likely to be formed, compared to the dippingmethod. Specifically, the total area of the “base exposed portions” islikely to be increased. This causes the mold release force to increasemore in the spraying method than in the dipping method. When the area ofthe individual base exposed portion is too great, the mold release forcebecomes excessive. As a result, the ceramic sheet is broken (the ceramicgreen sheet is non-releasable) when the ceramic green sheet is releasedfrom the molding die.

As described above, the method of applying the mold release agent inorder to form the film is made different, whereby the magnitude relationbetween the mold release force involved with the first molding die andthe mold release force involved with the second molding die can beadjusted (even if the type of the film and the average thickness are thesame).

The magnitude relation between the mold release force involved with thefirst molding die and the mold release force involved with the secondmolding die can be adjusted by making the thickness of the filmsdifferent, when the film is applied through the application of the moldrelease agent. When the thickness of the film is adjusted, the dippingmethod is preferable as the method of applying the mold release agent.This is based upon the operation in which the ultrathin film havingrelatively uniform thickness can be formed by the dipping method, andthe thickness of the film is easily adjusted, as described above.

When the ultrathin film is formed by the dipping method, the area of theabove-mentioned respective “base exposed portions” formed on “a greatnumber of microscopic protrusion portions formed on the molding surfacecorresponding to the surface roughness of the molding die” is morereduced, as the thickness of the film is increased. As a result, thetotal area of the “base exposed portions” is further reduced, so thatthe mold release force is more reduced. Therefore, the magnituderelation between the mold release force involved with the first moldingdie and the mold release force involved with the second molding die canalso be adjusted by making the thickness of the film different (even ifthe type of the film and the method of applying the mold release agentare the same).

In case where the magnitude relation between the mold release forceinvolved with the first molding die and the mold release force involvedwith the second molding die can be adjusted by making the thickness ofthe film, formed through the application of the mold release agent,different, the thickness of the film preferably falls within the rangeby which the relationship of 0.05·Rc≦t≦0.25·Rc″ is established, when thesurface roughness of the plane of the first and the second molding diesis defined as Rc (μm) by the average height, and the thickness of thefilm is defined as t (μm).

When the thickness of the film is too small, the total area of the baseexposed portion is too great (the mold release force is too great), sothat the ceramic green sheet is damaged when the ceramic green sheet isreleased (the ceramic green sheet is non-releasable). On the other hand,when the thickness of the film is too great, the base exposed portion iseliminated, so that the total area of the base exposed portion cannot beadjusted. Specifically, even if the thickness of the film is changed,the mold release force becomes fixed to be the minimum, so that the moldrelease force cannot be adjusted.

On the other hand, when the thickness of the film falls within the rangeby which the relationship of “0.05·Rc≦t≦0.25·Rc” is established, it hasbeen found that the ceramic green sheet can be released without damagingthe ceramic green sheet (the ceramic green sheet is releasable), and themold release force can be adjusted by changing the thickness of the filmas described later.

In the ceramic green sheet laminate, it is supposed that the portion,exposed on one of the surfaces of one ceramic green sheet of twoadjacent ceramic green sheets, of the body contained in the ceramicgreen sheet and the portion, exposed on one of the surfaces of the otherceramic green sheet that is opposite to the surface of the one ceramicgreen sheet, of the body contained in the other ceramic green sheet, areconnected to each other. In this case, a concave portion is formed onthe portion corresponding to the body on the plane, on which the body isformed, of one or both of the first and the second molding dies. Theportion of the body corresponding to the concave portion is molded intoa convex shape projecting from the plane of the ceramic green sheet.When the plane of the ceramic green sheet including the convex shape andthe plane of the adjacent ceramic green sheet are press-bonded, it ispreferable that the convex portion is pressed and crushed by the portionon the plane of the adjacent ceramic green sheet where the body,included in the adjacent ceramic green sheet, is exposed.

By virtue of this, the bodies included in the adjacent two ceramic greensheets are more surely be connected, compared to the case in which theportion corresponding to the convex shape on the body is molded into aplane shape that is continuous with the plane of the ceramic green sheetwithout having irregularities. As a result, the continuity of the shapecan more surely be secured in an electronic component (e.g., coil,inductor, coupler, antenna, etc.) having the above-mentioned continuouscomplicated three-dimensional shape or the space (cavity) having theabove-mentioned continuous complicated three-dimensional shape.

BRIEF DESCRIPTION OF THE DRAWINGS

Various other objects, features and many of the attendant advantages ofthe present invention will be readily appreciated as the same becomesbetter understood by reference to the following detailed description ofthe preferred embodiment when considered in connection with theaccompanying drawings, in which:

FIG. 1 is a perspective view showing an overall ceramic green sheetlaminate according to an embodiment of the present invention;

FIG. 2 is a plan view of ceramic green sheets used for producing theceramic green sheet laminate shown in FIG. 1;

FIG. 3 illustrates a process for producing one of the ceramic greensheets shown in FIG. 2;

FIG. 4 illustrates a process for producing another one of the ceramicgreen sheets shown in FIG. 2;

FIG. 5 shows a process for laminating the ceramic green sheets producedin the processes shown in FIGS. 3 and 4;

FIG. 6 shows a process for further laminating the other ceramic greensheets shown in FIG. 2 after the process shown in FIG. 5;

FIG. 7 shows that the order of the release of the first and secondmolding dies is appropriately controlled through the adjustment of amold release force and a sheet-to-sheet peeling force;

FIG. 8 shows a process for simultaneously producing plural ceramic greensheets shown in FIG. 1;

FIG. 9 is an exploded perspective view of a molding device used in theprocess shown in FIG. 8;

FIG. 10 is an assembly diagram showing the molding device used in theprocess shown in FIG. 8;

FIG. 11 shows how a ceramic slurry is injected by means of the moldingdevice shown in FIGS. 9 and 10;

FIG. 12 shows a process for producing one sheet, which corresponds to athick sheet obtained by superimposing two of the ceramic green sheetsshown in FIG. 2;

FIG. 13 shows a process for producing one sheet, which corresponds to athick sheet obtained by superimposing another two of the ceramic greensheets shown in FIG. 2;

FIG. 14 shows a process for laminating the ceramic green sheets producedin the processes shown in FIGS. 12 and 13;

FIG. 15 is a view, corresponding to FIGS. 12( a) and (b), showing thecase in which a concave portion is formed on the portion, correspondingto the body, of the molding surface of the second molding die having thebody formed thereon;

FIG. 16 is a view, corresponding to FIGS. 13( a) and (b), showing thecase in which a concave portion is formed on the portion, correspondingto the body, of the molding surface of the first molding die having thebody formed thereon;

FIG. 17 shows the process for laminating the ceramic green sheetsproduced in the processes shown in FIGS. 15 and 16;

FIG. 18 is a view, corresponding to FIG. 12, showing the case in whichthe ceramic slurry is molded into a thin flat plate with the state wherethe first and second bodies are respectively formed on both of themolding surfaces of the first and second molding dies, and the topsurfaces of the first and second bodies are spaced apart from each otherwith a predetermined distance;

FIG. 19 is a view showing the procedure of the experiment performed todetermine the “relationship between Rc and t” corresponding to theboundary between “releasable” and “non-releasable”;

FIG. 20 is a view showing the procedure of the experiment performed tofind out the “relationship between Rc and t” corresponding to theboundary between “the state in which the mold release force can beadjusted by changing the thickness of the film” and “the state in whichthe mold release force cannot be adjusted by changing the thickness ofthe film”; and

FIG. 21 is a graph showing the relationship between the concentration ofthe mold release agent and the thickness of the film.

DETAILED DESCRIPTION OF THE INVENTION

A production process of a ceramic green sheet, and a production processof a ceramic green sheet laminate according to the embodiment of thepresent invention will be described with reference to the drawings.

FIG. 1 is a perspective view showing a whole ceramic green sheetlaminate wherein plural (nine sheets in this example) ceramic greensheets according to the embodiment of the present invention are stackedand press-bonded. This laminate is small rectangular solid shaped and isseveral millimeters in square and height. The laminate has a body formedtherein (see a dark dot portion). The body has a continuous spiral formand is made of a precursor of a conductor. When the ceramic sheetlaminate (fired body) is formed by firing the ceramic green sheetlaminate, the body (the precursor of the conductor) having the spiralform becomes a conductor having the same shape. The conductor having thespiral form can serve as a minute coil (inductor, laminate inductor),antenna, etc. Therefore, the ceramic sheet laminate (fired body) havingthe conductor incorporated therein or its processed goods can be used asan electronic component incorporated in a cellular phone or the like.

The ceramic green sheet shown in FIG. 1 is obtained by laminating andpress-bonding nine flat-plate ceramic green sheets Za to Zi shown inFIG. 2 that is a plan view (top view), each having the same rectangularsolid form, and having uniform thickness, in the order from Za. Each ofthe ceramic green sheets Za to Zi is obtained by forming and solidifyinga ceramic slurry, containing a ceramic powder, dispersion medium, andgelling agent, into a flat-plate shape as described later. The ceramicgreen sheet may sometime be referred simply to a “sheet” hereinbelow.

Each of the sheets Za to Zi partially includes a body (shown as the darkdot portion) having a shape shown in FIG. 2 when viewed in a plane. Eachof the bodies is made of a precursor of a conductor obtained by moldingand solidifying a paste, which is made of a component different from thecomponent of the ceramic slurry as described later. The sectional shapeparallel to the sheet plane of each of the bodies is the same as theshape shown in FIG. 2 at any positions in the thickness direction of thesheet. Each of the bodies is exposed on a part of both surfaces (upperand lower surfaces) of the corresponding sheet with the same shape asthe shape shown in FIG. 2.

The shapes of the bodies included in the sheets Za to Zi are designedsuch that, for all combinations of the adjacent two sheets, respectiveportions of the respective bodies that are exposed to the opposing sideof an adjacent sheet are joined (brought into contact with) to eachother, when the sheets Za to Zi are stacked in order from Za to Zi. As aresult, when the sheets Za to Zi are stacked and press-bonded in orderfrom Za to Zi, the body (precursor of the conductor) having a continuousspiral form, as shown in FIG. 1, is formed.

The production process of each sheet shown in FIG. 2 and the productionprocess of the sheet laminate shown in FIG. 1 will be described belowwith reference to FIGS. 3 to 6. For the sake of convenience, FIGS. 3 to6 show an example (the example in which one sheet laminate is produced)in which a sheet is produced one by one. However, in actuality, aplurality of sheets (e.g., 25 sheets) are simultaneously produced asshown in FIGS. 8 to 11 described later (accordingly, a plurality ofsheet laminates are simultaneously formed). A first molding die A and asecond molding die B used for forming a sheet Z# are respectivelyreferred to as a first molding die A#, and a second molding die B# belowfor the sake of convenience. The symbol “#” indicates any one of “a” to“z” (the same is true below).

FIG. 3 shows the example in which the sheet Za (only one) is produced asone of the representatives of the sheets Za to Zi. Firstly, a firstmolding die Aa and a second molding die Ba, which have a rectangularsolid shape and are made of a plate-like aluminum alloy (e.g.,duralumin), are prepared. A mold release agent is applied to each of themolding surface (plane) of the first and the second molding dies Aa andBa so as to form a non-adherent film thereon.

The film is formed so as to adjust force (stress) (hereinafter referredto as “mold release force (mold release stress)”) in the thicknessdirection used for releasing the body molded on the molding surface fromthe molding surface. The greater the mold release force is, the moredifficult it is to release the body from the molding surface. In thepresent embodiment, the mold release force involved with the firstmolding dies Aa to Az is adjusted to be greater than the mold releaseforce involved with the second molding dies Ba to Bz. Additionally, themold release force of the first molding die Aa of the first molding diesAa to Az is adjusted to be greater than the mold release force involvedwith the remaining first molding dies Ab to Az. Further, the force inthe thickness direction (hereinafter referred to as “sheet-to-sheetpeeling force”) required for peeling the stacked and press-bonded sheetsis adjusted to be greater than the mold release force for the firstmolding die Aa.

Various films made of fluorine resin, silicon resin, fluorine oil, orsilicon oil, or made by plating, CVD, PVD, or the like, can be used asthe film. When fluorine resin, silicon resin, fluorine oil, or siliconoil is used for the film, the film is formed by a spraying method,dipping method, or the like. In this case, the mold release force can beadjusted according to the types of the resin, surface roughness of thefilm, or the thickness of the film.

When the film is formed by plating, fluorine resin, silicon resin,fluorine oil or silicon oil is preferably used. In this case, the moldrelease force is easy to be adjusted. When the film is formed by CVD orPVD, a gas containing fluorine atom may be used as a raw material. Inthis case, the mold release force is reduced so as to allow the moldrelease force to be easily adjusted. When the shape of the moldingsurface on which the film is formed is simple as in the presentembodiment (plane in the present embodiment), a resinous bulk material(plate material) may be adhered onto the molding surface. Alternatively,the die may be made of a resinous bulk material.

Subsequently, a paste, which is to be a conductor afterward (hereinafterreferred to as a “conductor paste”), is prepared. As shown in FIG. 3(a), the conductor paste is formed on the molding surface of the firstbody Aa, on which the film is formed so as to have the same shape as theshape of the body included in the sheet Za shown in FIG. 2 with thethickness same as (or slightly greater than) the thickness of the sheetZa according to a screen printing method or metal mask method.

The used conductive paste has conductive powders, resin component, andsolvent, which are appropriately mixed. Examples of the conductivepowders include metal powder such as silver powder, platinum powder.Examples of the resin component include resin such as phenolic resin,urethane resin, acrylic resin, butyral resin, ethyl cellulose, epoxyresin, theobromine resin, etc, or resin precursor. Examples of thesolvent include organic solvent such as butyl carbitol acetate, butylcarbitol, diethyl hexanol, terpineol, etc. The molded conductor paste(body) is solidified through a predetermined process. For example, whenthe paste contains phenolic resin, it is solidified through theapplication of heat.

Next, as shown in FIG. 3( b), the second molding die Ba is formed on themolding surface of the first molding die Aa on which the body is formedvia a spacer S having the thickness same as the thickness of the sheetZa. The second molding die Ba is placed with the molding surface onwhich the film is formed facing downward. Thus, the first and the secondmolding dies Aa and Ba are arranged in such a manner that the moldingsurface (plane) of the first molding die Aa on which the body is formedand the molding surface (plane) of the second molding die Ba (on whichthe body is not formed) oppose to each other so as to be parallel witheach other with a gap same as the thickness of the sheet Za, and the topsurface of the body (the plane having the shape same as the shape of thebody included in the sheet Za shown in FIG. 2 viewed in a plane) isbrought into contact with the molding surface of the second molding dieBa. The space H that is defined by the first and second molding dies Aaand Ba and the spacer S has the outline same as the outline of the sheetZa (rectangular solid).

Then, the ceramic slurry, which is to be a ceramic, is prepared. Theprepared ceramic slurry is filled in the space H as shown in FIG. 3( c).Thus, the ceramic slurry is molded so as to have the outline same as theoutline (rectangular solid) of the sheet Za.

The ceramic slurry contains a ceramic powder, dispersion medium, andgelling agent. The ceramic slurry also contains a dispersion aid or acatalyst as needed. The gelling agent solidifies the ceramic powder andallows the ceramic powder to be integral with the body, whereby theceramic green sheet can be obtained. The gelling agent also serves as abinder for bonding the ceramic green sheets upon the stacking.

The used ceramic slurry contains 100 parts by weight of ferrite powderserving as the ceramic powder, 27 parts by weight of a mixture ofaliphatic polyester and polybasic acid ester, 0.3 parts by weight ofethylene glycol serving as the dispersion medium, 3 parts by weight ofpolycarboxylic copolymer serving as the dispersion aid, 5.3 parts byweight of 4,4′-diphenyl methane diisocyanate serving as the gellingagent, and 0.05 parts by weight of 6-dimethylamino-1-hexanol serving asthe catalyst. The molded ceramic slurry is solidified through thepredetermined process. As a result, the sheet Za is obtained with thefirst and second molding dies Aa and Ba adhered onto both surfaces inthe thickness direction.

Alumina, zirconia, silica, ferrite, barium titanate, silicon nitride,silicon carbide, etc. may be used as the ceramic powder. Organic solventsuch as aliphatic polyester, polybasic acid ester, toluene, xylene,methyl ethyl ketone, etc. may be used as the dispersion medium. Phenolicresin, urethane resin, or acrylic resin, or a precursor thereof may beused as the gelling agent. An organic compound such as polycarboxyliccopolymer, sorbitan ester, etc. may be used as the dispersion aid. Anamine compound such as 6-dimethylamino-1-hexanol may be used as thecatalyst.

Next, as shown in FIG. 3( d), only the second molding die Ba is removedfrom the sheet Za having the first and the second molding dies Aa and Baadhered thereon. As described above, the mold release force involvedwith the first molding die Aa is adjusted so as to be greater than themold release force involved with the second molding die Ba. Accordingly,when the tensile force is applied to the first and the second moldingdies Aa and Ba in the direction in which the first and second moldingdies Aa and Ba are apart from each other in the thickness direction(vertical direction), only the second molding die Ba can easily beremoved. In this manner, the sheet Za having only the first molding dieAa adhered thereon is obtained as shown in FIG. 3( d).

FIG. 4 shows the example in which the sheet Zb (only one) is produced asthe representative of the sheets Za to Zi. FIGS. 4( a) to 4(d)correspond to the above-mentioned FIGS. 3( a) to 3(d) respectively. Theproduction process of the sheet Zb shown in FIGS. 4( a) to 4(d) is thesame as the production process of the sheet Za shown in FIGS. 3( a) to3(d) except that the conductor paste is molded on the molding surface ofthe first molding die Ab, on which the film is formed, in the shape sameas the shape of the body included in the sheet Zb with the thicknessequal to (or slightly greater than) the thickness of the sheet Zb.Therefore, the detail description of the production process shown inFIGS. 3( a) to 3(d) will not be repeated. In this manner, the sheet Zbhaving the first molding die Ab adhered thereon is obtained as shown inFIG. 4( d).

The sheets Zc to Zi can be obtained by the production process same asthe production process of the sheets Za and Zb described above. In thismanner, the sheet Z# (nine in total) (having only the first molding dieA# adhered thereon) shown in FIG. 2 is obtained. The reason why thefirst molding die A# is not removed from the sheet Z# in this stage(before the lamination of the sheet) is to facilitate the removal of thesheet during the stacking of the sheet as described later.

Next, the process for obtaining the sheet laminate shown in FIG. 1through the stacking and press-bonding of the sheet Z# will bedescribed. Firstly, as shown in FIG. 5( a), the sheet Zb having thefirst molding die Ab adhered thereon shown in FIG. 4( d) is turned over,whereby the plane of the sheet Zb that is exposed due to the removal ofthe second molding die Bb is superimposed and press-bonded to the planeof the sheet Za that is exposed due to the removal of the second moldingdie Ba. As a result, the laminate (number of laminated layers is 2) ofthe sheets Za and Zb is obtained with the first molding dies Aa and Abadhered onto both surfaces thereof in the thickness direction.

Then, as shown in FIG. 5( b), only the first molding die Ab is removedfrom the laminate of the sheets Za and Zb having the first molding diesAa and Ab adhered thereon. In this case, the mold release force involvedwith the first molding die Aa is adjusted to be greater than the moldrelease force involved with the first molding die Ab, and thesheet-to-sheet peeling force is adjusted to be greater than the moldrelease force involved with the first molding die Aa. Therefore, whenthe tensile force is applied to the first and molding dies Aa and Ab inthe direction in which the first molding dies Aa and Ab are apart fromeach other in the thickness direction (vertical direction), only thefirst molding die Ab can easily be removed. In this manner, the laminateof the sheets Za and Zb (number of laminated layers is 2) having onlythe first molding die Aa adhered thereon is obtained as shown in FIG. 5(b).

Next, the sheet Zc is stacked and press-bonded on the laminate of thesheets Za and Zb (number of laminated layers is 2) according to theprocedure shown in FIGS. 5( a) and 5(b). As a result, the laminate ofthe sheets Za, Zb, and Zc (number of laminated layers is 3) having onlythe first molding die Aa adhered thereon is obtained. By repeating theprocedure described above, the laminate of the sheets Za to Zi (numberof laminated layers is 9) having only the first molding die Aa adheredthereon is obtained as shown in FIG. 6( a).

Then, as shown in FIG. 6( b), the first molding die Aa is removed fromthe laminate of the sheets Za to Zi (number of laminated layers is 9)having only the first molding die Aa adhered thereon. In this case, thesheet-to-sheet peeling force is adjusted to be greater than the moldrelease force involved with the first molding die Aa as described above.Therefore, when the tensile force is applied to the first molding die Aain the direction in which the first molding die Aa is apart from thelaminate of the sheets Za to Zi in the thickness direction (verticaldirection), only the first molding die Aa can easily be removed. In thismanner, the ceramic green sheet laminate of the sheets Za to Zi shown inFIG. 1 (number of laminated layers is 9) is obtained as shown in FIG. 6(b).

FIG. 7 is a view for explaining the case in which the mold release forceand the sheet-to-sheet peeling force are adjusted as described above soas to appropriately control the order of the mold release of the firstand second molding dies A# and B#. In FIG. 7, among the segmentscorresponding to the molding surfaces of the molding die, the boldersegments indicate that the mold release force is small. For the sake ofconvenience, FIG. 7 illustrates the case in which the laminate made ofthree sheets Za, Zb, and Zc, which are representatives of nine sheets Zato Zi, is formed. The mark “*” indicates any one of “a” to “c” (the sameis true below).

In FIG. 7( a), the sheet Z* is simultaneously formed with the first andthe second molding dies A* and B* adhered on both surfaces thereof inthe thickness direction. The state shown in FIG. 7( a) corresponds tothe states shown in FIG. 3( c) and FIG. 4( c).

In FIG. 7( b), only the second molding die B* is removed from the sheetZ* having the first and the second molding dies A* and B* adheredthereon. The state shown in FIG. 7( b) corresponds to the states shownin FIG. 3( d) and FIG. 4( d). In this case, the mold release forceinvolved with the first molding die A* is adjusted to be greater thanthe mold release force involved with the second molding die B* asdescribed above. Therefore, when the tensile force is applied to thefirst and second molding dies A* and B* in the direction in which thefirst and second molding dies A* and B* are apart from each other in thethickness direction (vertical direction), only the second molding die B*can easily be removed.

In FIG. 7( c), the sheet Zb (see FIG. 7( b)) having the first moldingdie Ab adhered thereon is turned over, whereby the plane of the sheet Zathat is exposed due to the removal of the second molding die Ba issuperimposed and press-bonded to the plane of the sheet Zb that isexposed due to the removal of the second molding die Bb. As a result,the laminate (number of laminated layers is 2) of the sheets Za and Zbis obtained with the first molding dies Aa and Ab adhered onto bothsurfaces thereof in the thickness direction. The state shown in FIG. 7(c) corresponds to the state shown in FIG. 5( a).

In FIG. 7( d), only the first molding die Ab is removed from thelaminate of the sheets Za and Zb having the first molding dies Aa and Abadhered thereon. In this case, the mold release force involved with thefirst molding die Aa is adjusted to be greater than the mold releaseforce involved with the first molding dies Ab and Ac, and thesheet-to-sheet peeling force is adjusted to be greater than the moldrelease force involved with the first molding die Aa. Therefore, whenthe tensile force is applied to the first and molding dies Aa and Ab inthe direction in which the first molding dies Aa and Ab are apart fromeach other in the thickness direction (vertical direction), only thefirst molding die Ab can easily be removed.

In FIG. 7( e), the sheet Zc (see FIG. 7( b)) having the first moldingdie Ac adhered thereon is turned over, whereby the plane of the sheet Zcthat is exposed due to the removal of the second molding die Bc issuperimposed and press-bonded to the plane (i.e., the plane of the sheetZb) of the laminate of the sheets Za and Zb, which is exposed due to theremoval of the first molding die Ab. As a result, the laminate (numberof laminated layers is 3) of the sheets Za, Zb, and Zc is obtained withthe first molding dies Aa and Ac adhered onto both surfaces thereof inthe thickness direction.

In FIG. 7( f), only the first molding die Ac is removed from thelaminate of the sheets Za, Zb, and Zc having the first molding dies Aaand Ac adhered thereon. In this case, the mold release force involvedwith the first molding die Aa is adjusted to be greater than the moldrelease force involved with the first molding dies Ab and Ac, and thesheet-to-sheet peeling force is adjusted to be greater than the moldrelease force involved with the first molding die Aa as described above.Therefore, when the tensile force is applied to the first molding diesAa and Ac in the direction in which the first molding dies Aa and Ac areapart from each other in the thickness direction (vertical direction),only the first molding die Ac can easily be removed.

Then, as shown in FIG. 7( g), the first molding die Aa is removed fromthe laminate of the sheets Za, Zb, and Zc (number of laminated layers is3) having only the first molding die Aa adhered thereon. In this case,the sheet-to-sheet peeling force is adjusted to be greater than the moldrelease force involved with the first molding die Aa as described above.Therefore, when the tensile force is applied to the first molding die Aain the direction in which the first molding die Aa is apart from thelaminate of the sheets Za, Zb, and Zc in the thickness direction(vertical direction), only the first molding die Aa can easily beremoved. In this manner, the ceramic green sheet laminate of the sheetsZa, Zb, and Zc (number of laminated layers is 3) is formed.

As explained above, the order of the mold release of the molding dies A*and B* is appropriately controlled by adjusting the mold release forceand sheet-to-sheet peeling force. As a result, the sheet Z* can bestacked one by one by holding the molding die, not by holding the sheetZ* itself. Consequently, the ceramic green sheet is easy to handle.

In the above description, the example in which the sheet is produced oneby one (the example in which one sheet laminate is produced) has beendescribed for the sake of convenience. In actuality, the plural sheetsare simultaneously produced (accordingly, plural sheet laminates aresimultaneously produced) as shown in FIGS. 8 to 11. FIGS. 8 to 11illustrate the case in which the 25 sheets Za, 25 sheets Zb, and 25sheets Zc, which are the representatives of nine sheets Za to Zi, aresimultaneously formed, and 25 sheet laminates (number of laminatedlayers is 3) are simultaneously formed.

In FIG. 8( a), a mold release agent is applied to each of the moldingsurfaces of the first and second molding dies A* and B* used for moldingthe sheets Za, Zb, and Zc, whereby the film is formed on each of themolding surfaces. The mold release force is adjusted as described above.

In FIG. 8( b), the conductor paste is molded on the molding surface ofthe first molding die A* on which the film is formed in such a mannerthat 25 shapes each corresponding to the body included in the sheet Z*shown in FIG. 2 are aligned in a matrix of 5×5 with a predeterminedspace by means of a screen printing method. FIG. 8( b) corresponds toFIGS. 3( a) and 4(a).

In FIG. 8( c), the above-mentioned ceramic slurry is filled in the spaceH* that is defined by utilizing the first and second molding dies A* andB* and the spacer S (not shown in FIG. 8( c)). The outline of the spaceH* is the same as the outline (rectangular solid) of one big sheet ZZ*obtained when 25 sheets Z* are arranged without a gap on the same planein a matrix of 5×5. Thus, the ceramic slurry is molded into threerectangular solids having the outline same as the shape of the outline(rectangular solid) of the sheet ZZ*. FIG. 8( c) corresponds to FIGS. 3(c) and 4(c).

The process shown in FIG. 8( c) will be described below with referenceto FIGS. 9 to 11. In the process shown in FIG. 8( c), a molding deviceshown in FIG. 9 that is an exploded perspective view and FIG. 10 that isan assembly view is used. As shown in FIGS. 9 and 10, in the moldingdevice, a side wall member C formed with a slurry injection port Ca, aside wall member D, and a bottom wall member E formed with a slurrystorage section Ea are used in addition to the first and second moldingdies A* and B* and the spacer S.

In the condition in which the molding device is assembled as shown inFIG. 10, the first and the second molding dies A* and B* are arranged soas to stand in the vertical direction with spacers S in such a mannerthat the molding surface (plane) of the first molding die A* on which 25bodies are formed and the molding surface (plane) of the second moldingdie B* (on which the body is not formed) oppose to each other so as tobe parallel with each other with a gap same as the thickness of thesheet Z*, and the top surfaces of the 25 bodies are brought into contactwith the molding surface of the second molding die B*. The space H* isdefined by the first and second molding dies A* and B* and the spacer Sin this state.

In order to fill the space H* with the ceramic slurry, the ceramicslurry is injected into the slurry injection port Ca as indicated by abold arrow in FIG. 10. The injected ceramic slurry is filled in thespace H* from the bottom to the top through the cylindrical slurrypassage Cb extending downward from the injection port Ca formed in theside wall member C and the slurry storage section Ea.

In this case, after the predetermined amount of the ceramic slurry isinjected from the injection port Ca as shown in FIG. 11( a), the liquidlevel of the ceramic slurry in the slurry passage Cb is pressed down bythe application of pressure as shown in FIG. 11( b). Thus, the liquidlevel of the ceramic slurry in each space H* is pushed up, resulting inthat the ceramic slurry is filled in the whole space H*.

In this case, be careful that the liquid level in the slurry passage Cb(accordingly, the liquid level in the slurry storage section Ea) duringthe application of pressure does not lower the lower end of the space H*(refer to a straight line L-L) as shown in FIG. 11( c). This is becauseair bubbles might enter the space H*.

In order to prevent the liquid level in the slurry passage Cb fromlowering the lower end of the space H*, it is considered that moreamount of the ceramic slurry injected from the injection port Ca is set.Alternatively, the molding device is tilted such that the slurry passageCb moves upward as shown in FIG. 11( d).

Referring again to FIG. 8, the sheet ZZb including 25 bodies and thesheet ZZc including 25 bodies are stacked and press-bonded one by one inFIG. 8( d) onto the sheet ZZa including 25 bodies according to theprocedure similar to the procedure shown in FIGS. 5 and 6.

As a result, a ceramic green sheet laminate (number of laminated layersis 3) made of the sheets ZZa, ZZb, and ZZc is formed. This laminate iscut in a matrix of 5×5 in the direction perpendicular to the thicknessdirection, whereby the laminate is divided into 25 laminates (number oflaminated layers is 3). Consequently, 25 laminates (number of laminatedlayers is 3) made of the sheets Za to Zc shown in FIG. 2 aresimultaneously formed.

The process of forming the ceramic green sheet shown in FIG. 1 bystacking and press-bonding nine sheets Za to Zi shown in FIG. 2 from theorder from Za has been described above. In the process, the ceramicslurry is molded in a flat-plate shape with the body formed only on thefirst molding die A# of the first and the second molding dies A# and B#.On the other hand, the ceramic slurry may be molded in a flat-plateshape with the body formed on both of the first and second molding diesA# and B#. One example of a process for forming the ceramic greenlaminate shown in FIG. 1 by employing this technique will be describedbelow with reference to FIGS. 12 to 14.

FIGS. 12( a) to 12(d) correspond to FIGS. 3( a) to 3(d), and FIGS. 4( a)to 4(d). FIG. 12 shows the case in which a thick single sheet Zab (onlyone), which is obtained by superimposing the sheet Zb onto the sheet Za,is produced as one of the representatives of the sheets Za to Zi.

Firstly, as shown in FIG. 12( a), the conductor paste is molded on themolding surface of the first molding die Aa, on which the film isformed, so as to have the shape same as the shape of the body includedin the sheet Za shown in FIG. 2 with the thickness same as (or slightlygreater than) the thickness of the sheet Za according to a screenprinting method. Further, the conductor paste is molded on the moldingsurface of the second molding die Ba, on which the film is formed, so asto have the shape same as the shape of the body included in the sheet Zbshown in FIG. 2 with the thickness same as (or slightly greater than)the thickness of the sheet Zb according to a screen printing method. Themolded conductor paste (body) is solidified through a predeterminedprocess.

Then, the second molding die Ba is placed on the molding surface of thefirst molding die Aa on which the body (first body) is formed via aspacer S having the thickness same as the sum of the thickness of thesheet Za and the thickness of the sheet Zb as shown in FIG. 12( b). Thesecond molding die Ba is placed with the molding surface on which thebody (second body) is formed facing downward. Thus, the first and thesecond molding dies Aa and Ba are arranged in such a manner that themolding surface (plane) of the first molding die Aa on which the firstbody Aa is formed and the molding surface (plane) of the second moldingdie Ba on which the second body (Ba) is formed oppose to each other soas to be parallel with each other with a gap same as the sum of thethickness of the sheet Za and the thickness of the sheet Zb, and the topsurfaces of the first and second bodies are brought into contact witheach other. The space H that is defined by the first and second moldingdies Aa and Ba and the spacer S has the outline same as the outline ofthe sheet Zab (rectangular solid).

Then, the ceramic slurry is filled in the space H as shown in FIG. 12(c). Thus, the ceramic slurry is molded so as to have the outline same asthe outline (rectangular solid) of the sheet Zab. The molded ceramicslurry is solidified through the predetermined process. As a result, thesheet Zab having the first and second molding dies Aa and Ba adhered onboth ends in the thickness direction is formed.

Subsequently, as shown in FIG. 12( d), only the second molding die Ba isremoved from the sheet Zab having the first and second molding dies Aaand Ba adhered thereon. In this manner, the sheet Zab having only thefirst molding die Aa adhered thereon is obtained as shown in FIG. 12(d).

FIG. 13 shows the case in which a thick single sheet Zcd (only one),which is obtained by superimposing the sheet Zd onto the sheet Zc, isproduced as one of the representatives of the sheets Za to Zi. FIGS. 13(a) to 13(d) correspond to FIGS. 12( a) to 12(d). The production processof the sheet Zcd shown in FIGS. 13( a) to 13(d) is the same as theproduction process of the sheet Zab shown in FIGS. 12( a) to 12(d)except that the conductor paste is formed on the molding surface of thefirst molding die Ac, on which the film is formed, so as to have theshape same as the shape of the body included in the sheet Zc shown inFIG. 2 with the thickness same as (or slightly greater than) thethickness of the sheet Zc, and the conductor paste is formed on themolding surface of the second molding die Bc, on which the film isformed, so as to have the shape same as the shape of the body includedin the sheet Zd shown in FIG. 2 with the thickness same as (or slightlygreater than) the thickness of the sheet Zd. Therefore, the detaileddescription of the production process of the sheet Zcd shown in FIGS.13( a) to 13(d) will not be repeated. In this manner, the sheet Zcdhaving only the first molding die Ac adhered thereon is obtained asshown in FIG. 13( d).

One sheet Zef, which corresponds to a thick sheet obtained bysuperimposing the sheet Zf onto the sheet Ze, and one sheet Zgh, whichcorresponds to a thick sheet obtained by superimposing the sheet Zh ontothe sheet Zg, can be formed by the production process same as that ofthe sheets Zab and Zcd.

Next, as shown in FIG. 14( a) corresponding to FIG. 5( a), the sheet Zcdhaving the first molding die Ac adhered thereon shown in FIG. 13( d) isturned over, whereby the plane of the sheet Zcd that is exposed due tothe removal of the second molding die Bc is superimposed andpress-bonded to the plane of the sheet Zab that is exposed due to theremoval of the second molding die Ba. As a result, the laminate (numberof laminated layers is 2) of the sheets Zab and Zcd is obtained with thefirst molding dies Aa and Ac adhered onto both ends in the thicknessdirection.

Then, as shown in FIG. 14( b) corresponding to FIG. 5( b), only thefirst molding die Ac is removed from the laminate of the sheets Zab andZcd having the first molding dies Aa and Ac adhered thereon. In thismanner, the laminate of the sheets Zab and Zcd (number of laminatedlayers is 2) having only the first molding die Aa adhered thereon isobtained as shown in FIG. 14( b).

Next, the sheets Zef, Zgh, and Zi are stacked and press-bonded on thelaminate of the sheets Zab and Zcd (number of laminated layers is 2)according to the procedure shown in FIGS. 14( a) and 14(b). As a result,the laminate of the sheets Zab, Zcd, Zef, Zgh, and Zi (number oflaminated layers is 5) having only the first molding die Aa adheredthereon is obtained.

Then, the first molding die Aa is removed from the laminate of thesheets Zab, Zcd, Zef, Zgh, and Zi (number of laminated layers is 5)having only the first molding die Aa adhered thereon. In this manner,even if the first and second bodies are formed on both of the moldingsurfaces of the first and second molding dies A# and B#, and the topsurfaces of the first and second bodies are brought into contact witheach other, the ceramic green sheet laminate (number of laminated layersis 5) substantially equal to the ceramic green sheet laminate (number oflaminated layers is 9) of the sheets Za to Zi shown in FIG. 1 isobtained.

The case in which the molding surfaces of the first and second moldingdies are entirely plane without having irregularities has been describedabove. In this case, the portion exposed on the surface of the sheet inthe body (the precursor of the conductor) is molded in a plane shapethat is continuous with the sheet plane without having irregularities.When the portions of the bodies (precursor of the conductor), which areincluded in the two adjacent sheets and exposed to the side opposite tothe other sheet, are bonded to each other, like the sheets Zab and Zcdshown in FIG. 14, the continuity of the shape of the body might beimperfect.

On the other hand, when a concave portion Q is formed at the portion,corresponding to the body, on the molding surface, on which the body(precursor of the conductor) is formed, of the first and second moldingdies Ac and Ba (or either one of the first and second molding dies) asshown in FIGS. 15( a) and 15(b) corresponding to FIGS. 12( a) and 12(b)and FIGS. 16( a) and 16(b) corresponding to FIGS. 13( c) and 13(d), theportion of the body corresponding to the concave portion Q is moldedinto a convex shape R that projects from the plane of the sheet.

As shown in FIGS. 17( a) and 17(b) corresponding to FIGS. 14( a) and14(b), the convex shape R is pressed and crushed by the portion of theplane of the adjacent sheet Zcd where the body is exposed, when theplane of the sheet Zab including the convex portion R and the plane ofthe adjacent sheet Zcd are press-bonded.

Thus, the bodies included in the adjacent two sheets can more surely bebonded. Consequently, the continuity of the shape of the body becomesmore accurate. For example, when the body is a precursor of theconductor as described above, the electric conductivity of the conductorafter the firing can surely be secured.

FIGS. 12 and 13 show the case in which the ceramic slurry is molded intoa flat-plate shape in a state where the first and second bodies areformed on both of the molding surfaces of the first and second moldingdies A# and B#, and the top surfaces of the first and second bodies arebrought into contact with each other. However, as shown in FIG. 18corresponding to FIGS. 12 and 13, the ceramic slurry may be molded intoa flat-plate shape in a state in which the first and second bodies areformed on both of the molding surfaces of the first and second moldingdies A# and B#, and the top surfaces of the first and second bodies areapart from each other with a predetermined distance.

In this case, as shown in FIG. 18( b), the second molding die Ba isplaced onto the molding surface of the first molding die Aa, on whichthe first body (precursor of the conductor) is formed, via a spacer Shaving the height greater than the sum of the thickness of the firstbody and the thickness of the second body. The second molding die Ba isplaced with the molding surface, on which the second body (precursor ofthe conductor) is formed, facing downward. Thus, the first and secondmolding dies Aa and Ba are arranged such that the molding surface(plane) of the first molding die Aa, on which the body is formed, andthe molding surface (plane) of the second molding die Bb, on which thebody is formed, oppose to each other so as to be parallel with eachother, and the top surfaces of the bodies are apart from each other. Thespace H defined by the first and second molding dies Aa and Ba and thespacer S has the outline same as the outline of the sheet Zp(rectangular solid).

Then, the ceramic slurry is filled in the space H as shown in FIG. 18(c). Thus, the ceramic slurry is molded so as to have the outline same asthe outline (rectangular solid) of the sheet Zp. The molded ceramicslurry is solidified through the predetermined process. As a result, thesheet Zp having the first and second molding dies Aa and Ba adhered onboth ends in the thickness direction is formed.

Subsequently, as shown in FIG. 18( d), only the second molding die Ba isremoved from the sheet Zp having the first and second molding dies Aaand Ba adhered thereon. In this manner, the sheet Zp having only thefirst molding die Aa adhered thereon is obtained as shown in FIG. 18(d). Thereafter, the first molding die Aa is removed from the sheet Zp.The first molding die Aa can be removed by executing the followingprocesses to the bonded portion of the sheet Zp and the first moldingdie Aa. Specifically, the processes include, for example, melting themold release agent, inserting a spatula-like tool into the bondedportion, or blowing air.

When the sheet Zp is fired to form the ceramic sheet (fired body), thebody (precursor of the conductor) becomes the conductor of the sameshape. Specifically, a condenser having a ceramic interposed between theconductors, which are arranged apart from each other with apredetermined distance, can be formed. Accordingly, the ceramic sheet(fired body) having this condenser incorporated therein or its processedproduct can be used as an electronic component incorporated in acellular phone or the like.

The case in which the body is made of the precursor of the conductor(conductor paste), which becomes the conductor when the ceramic sheet isformed by firing the ceramic green sheet, has been described above. Onthe other hand, the body may be made of a component that is removedthrough the volatilization when the ceramic sheet is formed by firingthe ceramic green sheet.

In this case, the paste obtained by mixing resin component such asphenolic resin, urethane resin, acrylic resin, butyral resin,theobromine, ethyl cellulose, epoxy resin, etc, or precursor of theseresins can be used as the paste used for molding the body. When theceramic sheet is formed through the firing of the laminate in the caseof the ceramic green sheet laminate shown in FIG. 1, for example, aspace (cavity) having a continuous spiral form can be obtained.

The body may be made of a precursor of the ceramic that becomes theceramic when the ceramic sheet is formed through the firing of theceramic green sheet. In this case, the paste obtained by mixing resincomponent such as phenolic resin, urethane resin, acrylic resin, butyralresin, theobromine, ethyl cellulose, epoxy resin, etc, or precursor ofthese resins and a ceramic powder such as alumina, zirconia, silica,ferrite, barium titanate, silicon nitride, silicon carbide, etc. can beused as the paste used for molding the body. Accordingly, when theceramic sheet is formed through the firing, a structure having a patternformed by the ceramic of different type incorporated therein can beformed in the ceramic sheet.

It is added below about the adjustment in the magnitude relation of themold release force involved with the first molding die and the moldrelease force involved with the second molding die. This adjustment isperformed for appropriately controlling the order of the mold release asexplained with reference to FIG. 7.

The magnitude relation between the mold release force involved with thefirst molding die and the mold release force involved with the secondmolding die can be adjusted by making different the type of the filmformed through the application of the mold release agent or surfacetreatment (coating) to the molding surfaces of the first and secondmolding dies. For example, when fluorine resin and wax are used as themold release agent, and a fluorine-containing nickel plating is employedas the surface treatment, the relationship of (mold release force in thecase of the wax)>(mold release force in the case of thefluorine-containing nickel plating)>(mold release force in the case ofthe fluorine resin) is established at room temperature as describedabove.

When the type of the film formed on the molding surfaces of the firstand second molding dies are made different, the magnitude relationbetween the mold release force involved with the first molding die andthe mold release force involved with the second molding die can beadjusted (even if the thickness of the film is the same).

When the film is formed through the application of the mold releaseagent, the magnitude relation between the mold release force involvedwith the first molding die and the mold release force involved with thesecond molding die can also be adjusted by making the method of applyingthe mold release agent different. Examples of the method of applying themold release agent include a spraying method and dipping method. Thesemethods are compared below. The “base exposed portion” is the portionwhere the surface of the base of the molding die is exposed on the planeof the molding die on which the film is formed as described above.

In general, in the case of the dipping method, a very thin film havingrelatively uniform thickness is formed. On the other hand, in the caseof the spraying method, the thickness of the film is non-uniformcompared to the dipping method. Specifically, the state of the filmformed by applying the mold release agent with the spraying method isrelatively sensitive to the concentration of the mold release agent,opening degree of a valve portion for adjusting the discharge rate (flowrate of the discharged spray), temperature of the molding die, etc.

More specifically, when the solution of the applied mold release agentis difficult to be dried, such as when the temperature of the moldingdie is low or when the amount of the discharge liquid is great, the flow(dripping) or aggregation of the solution of the mold release agent isgenerated. Accordingly, the irregularities are easy to generate on thesurface of the formed film. On the contrary, when the solution of theapplied mold release agent is easy to be dried, such as when thetemperature of the molding die is high or when the amount of thedischarge liquid is small, the solvent is volatilized before the levelof the solution of the mold release agent is leveled (smoothed).Therefore, the irregularities are also easy to generate on the surfaceof the formed film. Anyway, the irregularities are easy to generate onthe surface of the film, and hence, the thickness of the film isnon-uniform in the case of the spraying method, compared to the dippingmethod. This means that the surface area of the film is increased in thespraying method compared to the dipping method. By virtue of this, themold release force is increased more in the spraying method than in thedipping method

Additionally, since the ultrathin film having relatively a uniformthickness can be formed in the dipping method as described above, the“base exposed portion” can be formed on only a great number ofmicroscopic protrusion portions on the plane that correspond to thesurface roughness of the plane (molding surface) of the molding die. Inother words, only a great number of microscopic “base exposed portions”are dispersed, while relatively large “base exposed portions” aredifficult to be formed. On the other hand, the thickness of the filmbecomes non-uniform in the spraying method as described above.Therefore, when the ultrathin film is formed, the relatively large “baseexposed portions” are likely to be formed, compared to the dippingmethod. Specifically, the total area of the “base exposed portions” islikely to be increased. This causes the mold release force to increasemore in the spraying method than in the dipping method. When the area ofthe individual base exposed portion is too great, the mold release forcebecomes excessive. As a result, the ceramic sheet is broken (the ceramicsheet is non-releasable) when the ceramic green sheet is released fromthe molding die.

As described above, the method of applying the mold release agent inorder to form the film is made different, whereby the magnitude relationbetween the mold release force involved with the first molding die andthe mold release force involved with the second molding die can beadjusted (even if the type of the film and the average thickness are thesame). The variation range of the thickness of the film formed by thespraying method is about several micrometers. Therefore, it can be saidthat the film formed by the spraying method satisfactorily meets theproperty required as the molding surface of the ceramic green sheet.

The magnitude relation between the mold release force involved with thefirst molding die and the mold release force involved with the secondmolding die can be adjusted by making the thickness of the filmdifferent, when the film is applied through the application of the moldrelease agent. When the thickness of the film is adjusted, the dippingmethod is preferable as the method of applying the mold release agent.This is based upon the operation in which the ultrathin film havingrelatively uniform thickness can be formed by the dipping method, andthe thickness of the film is easily adjusted, as described above. Thethickness of the film can be adjusted by adjusting the concentration ofthe mold release agent, the speed (hereinafter referred to as “liftingspeed”) when the molding die is lifted after the molding die is dippedin the solution of the mold release agent, the temperature of themolding die, the temperature of the solution of the mold release agent,and the temperature of the environment. The relationship between theconcentration of the mold release agent and the thickness of the filmwill be described later.

When the ultrathin film is formed by the dipping method, the area of theabove-mentioned respective “base exposed portions” formed on “a greatnumber of microscopic protrusion portions formed on the molding surfacecorresponding to the surface roughness of the molding die” is morereduced, as the thickness of the film is increased. As a result, thetotal area of the “base exposed portions” is further reduced, so thatthe mold release force is more reduced.

Thus, the magnitude relation between the mold release force involvedwith the first molding die and the mold release force involved with thesecond molding die can be adjusted by making the thickness of the filmformed through the application of the mold release agent different (evenif the type of the film and the average thickness are the same).

The preferable range of the thickness of the film formed by the dippingmethod will be studied below. As mentioned above, the smaller thethickness of the film is, the larger the total area of the “base exposedportions” is (accordingly, the more the mold release force increases).Therefore, when the thickness of the film is too small, the total areaof the “base exposed portions” becomes too large, so that the moldrelease force becomes excessive. Consequently, the ceramic green sheetmight be broken (ceramic green sheet is non-releasable) when the ceramicgreen sheet is released from the molding die. On the contrary, when thethickness of the film is too great, the “base exposed portions” aredisappeared. As a result, the total area of the “base exposed portions”cannot be adjusted. Specifically, even if the thickness of the film ischanged, the mold release force becomes the minimum and constant, sothat the mold release force cannot be adjusted.

On the other hand, when the relationship of “0.05·Rc≦t≦0.25·Rc” isestablished in case where the surface roughness of the plane (surface ofthe base) of the second molding die is defined as Rc (μm) by the“average height (average height of irregularities” (JIS B0601:2001), andthe thickness of the film is defined as t (μm), it has been found thatthe ceramic green sheet can be released from the molding die withoutdamaging the ceramic green sheet (the ceramic green sheet isreleasable), and the mold release force can be adjusted by changing thethickness of the film. The experiment conducted by verifying this resultwill be described below.

FIG. 19 shows the procedure of the experiment for finding the“relationship between Rc and t” corresponding to the boundary between“releasable” (the state in which the ceramic green sheet can be releasedfrom the molding die without damaging the ceramic green sheet) and“non-releasable” (the state in which the ceramic green sheet is damagedwhen the ceramic green sheet is released from the molding die).

As shown in FIG. 19( a), a flat plate At (that is made of an aluminumalloy like the molding die used in the above-mentioned embodiment)having the top surface serving as the molding surface is firstlyprepared. The flat plate At has a rectangular solid form, in which theplane shape is a 50-mm-square and the thickness is 20 mm. The surfaceroughness of the base surface of the molding surface is Rc (μm) by the“average height” (JIS B0601:2001). A film (thickness: t (μm)) made of afluorine resin serving as a mold release agent is formed onto themolding surface with the dipping method.

Next, as shown in FIG. 19( b), the side face of the flat plate At isenclosed by an adhesive tape T, which has a width greater than thethickness of the flat plate At, in such a manner that the adhesive tapestands around the molding surface. Then, as shown in FIG. 19( c), aceramic slurry (the same as the one used in the above-mentionedembodiment) is injected onto the molding surface of the flat plate Atenclosed by the adhesive tape T so as to have a predetermined thickness,and then, the slurry is molded and solidified into a thin plate form(rectangular solid form). Thus, the thin-plate ceramic green sheet Zt isformed.

Next, as shown in FIG. 19( d), the adhesive tape T is gently peeled.Then, as shown in FIG. 19( e), external force is applied to the ceramicgreen sheet Zt in the thickness direction (refer to the direction shownby an arrow) with the flat plate At being fixed in order to release theceramic green sheet Zt from the flat plate At. In this case, it isdetermined that the ceramic green sheet is “releasable” or“non-releasable”. This determination is done by visually confirmingwhether the ceramic green sheet is damaged or not.

The procedure described above was repeatedly executed, while the“combination (standard) of Rc and t” is successively changed. Table 1shows the result. The “releasable” state is represented by “O”, and the“non-releasable state” is represented by “X”.

TABLE 1 Base surface of flat plate Rc μm 0.82 1.34 1.78 Thickness offilm of mold release 0.03 X X X agent t μm 0.05 ◯ X X 0.07 ◯ ◯ X 0.12 ◯◯ ◯ 0.18 ◯ ◯ ◯ 0.22 ◯ ◯ ◯ 0.30 ◯ ◯ ◯ 0.34 ◯ ◯ ◯ 0.38 ◯ ◯ ◯ 0.44 ◯ ◯ ◯0.51 ◯ ◯ ◯ ◯: releasable X: non-releasable (body is damaged)

From Table 1, it can be concluded that the ceramic green sheet is“releasable” when the relationship of “0.05·Rc≦t” is established, whilethe ceramic green sheet is “non-releasable” when the relationship of“t<0.05·Rc” is established.

FIG. 20 shows the procedure of the experiment that is conducted to findout the “relationship between Rc and t” corresponding to the boundarybetween the “state in which the mold release force can be adjusted bychanging the thickness of the film” (the state in which the area of thebase exposed portion can be adjusted by changing the thickness of thefilm) and “state in which the mold release force cannot be adjusted bychanging the thickness of the film” (the state in which the base exposedportion is eliminated, and hence, the area cannot be adjusted).

As shown in FIG. 20( a), two flat plates Ata and Atb (made of analuminum alloy like the molding die used in the above-mentionedembodiment) are prepared. For example, each of the flat plates Ata andAtb has a rectangular solid form, in which the plane shape is a50-mm-square and the thickness is 20 mm. The surface roughness of thebase surface of each molding surface is Rc (μm) by the “average height”(JIS B0601:2001). A film (thickness: t (μm)) made of a fluorine resinserving as a mold release agent is formed onto each of the moldingsurfaces with the dipping method. When the thickness of the film on theflat plate Ata is defined as t (μm), the thickness of the film on theflat plate Atb is t+α (μm) (α>0). Specifically, the thickness of thefilm on the flat plate Ata is greater than the thickness of the film onthe flat plate Atb. Accordingly, the mold release force involved withthe flat plate Ata must be greater than the mold release force involvedwith the flat plate Atb.

The two flat plates Ata and Atb are held in such a manner that therespective molding surfaces oppose to each other in parallel with apredetermined space (e.g., 2 mm), and both side surfaces and lowersurface around the space formed between the molding surfaces are sealedby means of tools F1, F2 and F3. A ceramic slurry (same as the one usedin the above-mentioned embodiment) is injected and filled in the spacefrom an opening formed on the top surface around the space. Then, theslurry is molded and solidified into a thin plate form (rectangularsolid form). Thus, a ceramic green sheet Zt having a thin plate form isformed.

Subsequently, as shown in FIG. 20( b), the tools F1, F2 and F3 aregently removed, and then, external force is applied to the flat platesAta and Atb in the thickness direction (refer to the direction shown bytwo arrows), whereby both plates are separated. When the ceramic greensheet Zt remain on the flat plate Ata as a result of the separation asshown in FIG. 20( c), this means that the mold release force involvedwith the flat plate Ata is greater than the mold release force involvedwith the flat plate Atb, accordingly, that the ceramic green sheet is in“the state in which the mold release force can be adjusted by changingthe thickness of the film”. On the other hand, when the ceramic greensheet Zt remain on the flat plate Atb, or when the ceramic green sheetZt remain on neither flat plate (when the ceramic green sheet Zt fallsby its own weight), this means that the ceramic green sheet is in “thestate in which the mold release force cannot be adjusted by changing thethickness of the film”.

The procedure described above is executed five times for one“combination (standard) of Rc and t”. This execution is repeatedlyperformed as “combination (standard) of Rc and t” is changed. The numberof times the ceramic green sheet Zt remains on the flat plate Ata iscounted for each standard. Table 2 shows the result. In this experiment,it is determined that the ceramic green sheet is in “the state in whichthe mold release force can be adjusted by changing the thickness of thefilm” when the counted number is “4” or more, and in other cases, it isdetermined that the ceramic green sheet is in “the state in which themold release force cannot be adjusted by changing the thickness of thefilm”.

TABLE 2 Base surface of flat plate Flat plate Flat plate Rc μm Ata Atb0.82 1.34 1.78 Thickness of 0.03 - 0.05 — — — film of mold 0.05 - 0.07 5— — release 0.07 - 0.12 5 5 — agent t μm 0.12 - 0.18 5 5 5 0.18 - 0.22 55 5 0.22 - 0.30 1 5 5 0.30 - 0.34 0 5 5 0.34 - 0.38 1 1 5 0.38 - 0.44 01 5 0.44 - 0.51 0 0 4 0.51 - 0.65 0 0 1

From Table 2, it can be concluded that the ceramic green sheet is in“the state in which the mold release force can be adjusted by changingthe thickness of the film” when the relationship of “t≦0.25·Rc” isestablished, while the ceramic green sheet is in “the state in which themold release force cannot be adjusted by changing the thickness of thefilm” when the relationship of “0.25·Rc<t” is established.

From the above, it can be concluded that the ceramic green sheet can bereleased (“releasable”) from the molding die without damaging theceramic green sheet and the mold release force can be adjusted bychanging the thickness of the film when the relationship of“0.05·Rc≦t≦0.25·Rc” is established between Rc and t.

The relationship between the concentration of the mold release agent andthe thickness of the film will be described with reference to FIG. 21.FIG. 21 shows the result of the experiment for acquiring therelationship between the concentration (percent by mass) of the moldrelease agent and the thickness (μm) of the film when the dipping methodis employed. In this experiment, the process for measuring the thicknessof the film, which is made of the fluorine resin serving as the moldrelease agent and formed on the surface (plane) of a predetermined glassplate with the dipping method, at room temperature is repeatedlyperformed as the concentration of the mold release agent is successivelychanged. The lifting speed is fixed to 1.0 mm/sec.

As can be understood from FIG. 21, the concentration of the mold releaseagent is substantially proportional to the thickness of the film in thedipping method within the range of 3 to 18% of the concentration of themold release agent. This means that the mold release force can beadjusted by changing the concentration of the mold release agent withinthe range of 3 to 18% of the concentration of the mold release agent.When the concentration of the mold release agent is 18(%), the moldrelease agent is precipitated in the solution of the mold release agent.Specifically, the upper limit of the concentration of the mold releaseagent is about 18(%).

In the dipping method, the thickness of the film is substantiallyuniform all over the film. On the other hand, the variation range of thethickness of the film is about 0.6 μm, and the minimum value of thethickness is 0.2 μm in the spraying method when the concentration of themold release agent is 3(%), as can be understood from FIG. 21.Specifically, although the film formed with the spraying method has agreat variation range compared to the film formed with the dippingmethod, the minimum value (=0.2 μm) of the thickness can be a sufficientvalue for realizing the “releasable” ceramic green sheet.

1. A ceramic green sheet having a thin flat plate shape defining twoopposed planar surfaces and having a uniform thickness therebetween thatis obtained by molding and solidifying a ceramic slurry, containing aceramic powder, a dispersion medium, and a gelling agent, selected fromthe group consisting of urethane resins and urethane resin precursors,that is solidified through a urethane reaction, into a thin flat plate,wherein the ceramic green sheet partially includes a body formed thereinthat is obtained by molding and solidifying a paste, which is made of acomponent different from the ceramic slurry, wherein a portion the bodyis exposed on a part of each of the two opposed planar surfaces of theceramic green sheet.
 2. A ceramic green sheet according to claim 1,wherein the body comprises at least two bodies, and wherein the portionof one of the at least two bodies that is exposed on a part of one ofthe opposed planar surfaces of the ceramic green sheet and the portionof another one of the at least two bodies that is exposed on a part ofthe other one of the opposed planar surfaces of the ceramic green sheetare not connected to each other.
 3. A ceramic green sheet according toclaim 1, wherein the portion of the body that is exposed on a part ofone of the opposed planar surfaces of the ceramic green sheet and theportion of the body that is exposed on a part of the other one of theopposed planar surfaces of the ceramic green sheet are connected to eachother.
 4. A ceramic green sheet laminate including two or more ceramicgreen sheets according to claim 3 stacked in the thickness direction,wherein for at least one combination of two adjacent ceramic greensheets, the portion of the body within a first one of the two adjacentceramic green sheets, which is exposed to and facing a second one of thetwo adjacent ceramic green sheets, and the portion of the body within asecond one of the two'adjacent ceramic green sheets, which is exposed toand facing the first one of the two adjacent ceramic green sheets, areconnected to each other.
 5. A ceramic green sheet according to claim 1,wherein the body is composed of a precursor of a conductor, whichbecomes a conductor when a ceramic sheet is later formed by firing theceramic green sheet.
 6. A ceramic green sheet according to claim 1,wherein the body is composed of a component that is completely removedthrough the volatilization when a ceramic sheet is later formed byfiring the ceramic green sheet.
 7. A ceramic green sheet according toclaim 1, wherein the body is composed of a precursor of a ceramic, whichbecomes a ceramic when a ceramic sheet is later formed by firing theceramic green sheet.
 8. A ceramic green sheet laminate according toclaim 4, wherein the body is composed of a precursor of a conductor,which becomes a conductor when a ceramic sheet is later formed by firingthe ceramic green sheet.
 9. A ceramic green sheet laminate according toclaim 4, wherein the body is composed of a component that is completelyremoved through the volatilization when a ceramic sheet is later formedby firing the ceramic green sheet.
 10. A ceramic green sheet laminateaccording to claim 4, wherein the body is composed of a precursor of aceramic, which becomes a ceramic when a ceramic sheet is later formed byfiring the ceramic green sheet.